Flow cell for operando X-ray photon-in-photon-out studies on photo-electrochemical thin film devices
نویسندگان
چکیده
Background: Photo-electro-chemical (PEC) water splitting represents a promising technology towards an artificial photosynthetic device but many fundamental electronic processes, which govern long-term stability and energetics, are not yet fully understood. X-ray absorption spectroscopy (XAS), particularly its high energy resolution fluorescence-detected (HERFD) mode, emerges as powerful tool to study photo-excited charge carrier behavior under operating conditions. The established thin film architecture of PEC cells provides well-defined measurement geometry, it puts constraints on conducting operando XAS experiments. It remains challenge establish standardized exchange procedure concurrently record high-quality photoelectrochemical X‑ray data that is unperturbed by bubble formation. Here we address overcome these instrumental limitations for operando HERFD-XAS. Methods: We constructed novel operando photo-electro-chemical cell computer numerical control milling, guided the materials’ visible light properties optimize signal detection. To test cell’s functionality, semiconducting photoelectrodes have been fabricated via solution deposition their responses simulated solar were studied using commercial potentiostat in three-electrode configuration during HERFD-XAS experiments at synchrotron. Results: We demonstrate capabilities measure potentiostatically open‑circuit, detect signals bubbles fluently different samples collecting high-resolution Fe K-edge spectra hematite (α -Fe2O3) ferrite (MFe2O4, M= Zn, Ni) oxidation. Conclusions: Our establishes routine will provide experimental access photo-electro-chemical HERFD-XAS broader scientific community, due ease sample exchange. We believe enable broad range acquired insights spur further research commercialization technologies
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ژورنال
عنوان ژورنال: Open research Europe
سال: 2022
ISSN: ['2732-5121']
DOI: https://doi.org/10.12688/openreseurope.14433.2